Brassell, Simon C. et al. (2002): Organic geochemistry of the early Aptian OAE1A from Shatsky Rise (ODP Leg 198)

Leg/Site/Hole:
ODP 198
ODP 198 1207
ODP 198 1213
Identifier:
2004-037741
georefid

Creator:
Brassell, Simon C.
Indiana University, Department of Geological Sciences, Bloomington, IN, United States
author

Bralower, T. J.
author

Premoli Silva, I.
author

Malone, M. J.
author

Arthur, M. A.
author

Averyt, K.
author

Brwn, P.
author

Channell, J. E. T.
author

Clarke, L. J.
author

Dutton, A. L.
author

Eleso, J. W.
author

Frank, T. D.
author

Gylesjo, S.
author

Hancock, H.
author

Kano, H.
author

Leckie, R. Mark
author

Marsaglia, K. M.
author

McGuire, J.
author

Moe, K. T.
author

Petrizzo, M. R.
author

Robinson, S.
author

Roel, U.
author

Sager, W. W.
author

Tadeka, K.
author

Thomas, D.
author

Williams, T.
author

Zachos, J. C.
author

Identification:
Organic geochemistry of the early Aptian OAE1A from Shatsky Rise (ODP Leg 198)
2002
In: Anonymous, Geological Society of America, Southeastern Section, 51st annual meeting; Geological Society of America, North-Central Section, 36th annual meeting
Geological Society of America (GSA), Boulder, CO, United States
34
2
45
Series of mid-Cretaceous organic-rich claystones and porcellanites were recovered during ODP Leg 198 on Shatsky Rise in the west-central Pacific. The abundance, nature, and origin of the organic matter in select intervals were examined by shipboard procedures employing elemental analysis, Rock-Eval pyrolysis, and gas chromatography-mass spectrometry (GC-MS). Remarkable amounts of organic carbon (up to 35% Corg) occur within the early Aptian Oceanic Anoxic Event (OAE 1a) at Sites 1207 and 1213, which are among the highest values ever recorded for pelagic Cretaceous sequences. They attest to the extraordinary nature of the depositional conditions that led to enhanced sequestration of type I kerogen rich in algal and bacterial organic matter. The biomarker composition of the intervals provides clear testimony of the exceptional preservation of organic matter, both in its abundance and unaltered character. The hydrocarbon and ketone biomarkers show stratigraphic consistency in the compositions of compounds attributed to eukaryotes (notably sterenes and sterones), but variability in prokaryotic (especially hopanoid) distributions and abundances. The constituents included unprecedented series of 2-methyl-17beta (H),21beta (H) hopanes and hopanones diagnostic of cyanobacterial contributions. Alkenones, components only biosynthesized by haptophyte algae, occur in one of the lower Aptian samples, which extends the geological record of the occurrence of these paleotemperature proxies by 15 My. These preliminary results provide evidence of the biological origins of the organic matter in selected intervals of the early Aptian and help describe their environment of deposition, including the dysoxic conditions. They suggest changes in prokaryote populations related to the conditions that led to increased sequestration of organic matter and help describe the phytoplankton communities extant during OAE 1a. The authors of this paper include the ODP Leg 198 Shipboard Scientific Party: T.J. Bralower, I. Premoli-Silva, M.J. Malone, M.A. Arthur, K. Averyt, P. Bown, J.E.T. Channell, L.J. Clarke, A.L. Dutton, J.W. Eleson, T.D. Frank, S. Gylesjoe, H. Hancock, H. Kano, R.M. Leckie, K.M. Marsaglia, J. McGuire, K.T. Moe, M.R. Petrizzo, S. Robinson, U. Roehl, W.W. Sager, K. Takeda, D. Thomas, T. Williams, and J.C. Zachos.
English
Coverage:Geographic coordinates:
North:37.4800
West:162.4500East: 162.4600
South:37.4700

Geochemistry of rocks, soils, and sediments; Stratigraphy; algae; Aptian; bacteria; chemical composition; clastic rocks; claystone; Cretaceous; kerogen; Leg 198; Lower Cretaceous; Mesozoic; microfossils; North Pacific; Northwest Pacific; Ocean Drilling Program; ODP Site 1207; ODP Site 1213; organic compounds; Pacific Ocean; paleoclimatology; paleoecology; paleotemperature; Plantae; porcellanite; sedimentary rocks; Shatsky Rise; West Pacific;

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