Malone, Mitchell J. et al. (2001): Early diagenesis of shallow-water periplatform carbonate sediments, leeward margin, Great Bahama Bank (Ocean Drilling Program Leg 166)

Leg/Site/Hole:
ODP 166
ODP 166 1008
ODP 166 1009
Identifier:
2001-049728
georefid

Creator:
Malone, Mitchell J.
Texas A&M University, Ocean Drilling Program, College Station, TX, United States
author

Slowey, Niall C.
Oxford University, United Kingdom
author

Henderson, Gideon M.
author

Identification:
Early diagenesis of shallow-water periplatform carbonate sediments, leeward margin, Great Bahama Bank (Ocean Drilling Program Leg 166)
2001
Geological Society of America Bulletin
Geological Society of America (GSA), Boulder, CO, United States
113
7
881-894
Mineralogic, petrographic, and geochemical analyses of sediments recovered from two Leg 166 Ocean Drilling Program cores on the western slope of Great Bahama Bank (308 m and 437 m water depth) are used to characterize early marine diagenesis of these shallow-water, periplatform carbonates. The most pronounced diagenetic products are well-lithified intervals found almost exclusively in glacial lowstand deposits and interpreted to have formed at or near the seafloor (i.e., hardgrounds). Hardground cements are composed of high-Mg calcite ( approximately 14 mol% MgCO (sub 3) ), and exhibit textures typically associated with seafloor cementation. Geochemically, hardgrounds are characterized by increased delta (super 18) O and Mg contents and decreased delta (super 13) C, Sr, and Na contents relative to their less lithified counterparts. Despite being deposited in shallow waters that are supersaturated with the common carbonate minerals, it is clear that these sediments are also undergoing shallow subsurface diagenesis. Calculation of saturation states shows that pore waters become undersaturated with aragonite within the upper 10 m at both sites. Dissolution, and likely recrystallization, of metastable carbonates is manifested by increases in interstitial water Sr and Sr/Ca profiles with depth. We infer that the reduction in mineral saturation states and subsequent dissolution are being driven by the oxidation of organic matter in this Fe-poor carbonate system. Precipitation of burial diagenetic phases is indicated by the down-core appearance of dolomite and corresponding decrease in interstitial water Mg, and the presence of low-Mg calcite cements observed in scanning electron microscope photomicrographs.
English
Serial
Coverage:Geographic coordinates:
North:23.3650
West:-79.0501East: -79.0300
South:23.3638

Isotope geochemistry; Oceanography; alkali metals; alkaline earth metals; Atlantic Ocean; C-13/C-12; carbon; carbonate platforms; carbonate sediments; carbonates; cement; cementation; cores; diagenesis; early diagenesis; electron probe data; experimental studies; geochemistry; Great Bahama Bank; hardground; isotope ratios; isotopes; Leg 166; magnesium; marine sediments; metals; North Atlantic; O-18/O-16; Ocean Drilling Program; ODP Site 1008; ODP Site 1009; organic compounds; oxidation; oxygen; pore water; precipitation; saturation; sediments; SEM data; shallow-water environment; sodium; solution; stable isotopes; strontium; textures;

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