Hopkinson, L. J. et al. (2000): Moving reactive interfaces and fractal carbonate replacement patterns in serpentinites; evidence from the southern Iberia abyssal plain

Leg/Site/Hole:
ODP 173
Identifier:
2001-000744
georefid

Creator:
Hopkinson, L. J.
University of Southampton, School of Ocean and Earth Science, Southampton, United Kingdom
author

Dee, S.
Alastair Beach Associates, United Kingdom
author

Boulter, C. A.
author

Identification:
Moving reactive interfaces and fractal carbonate replacement patterns in serpentinites; evidence from the southern Iberia abyssal plain
2000
Mineralogical Magazine
Mineralogical Society, London, United Kingdom
64
5(426)
791-800
Serpentinized ultramafic rocks recovered from beneath the southern Iberia Abyssal Plain (Ocean Drilling Programme Leg 173) provide the first record of fractal carbonate replacement patterns in a serpentinite. The patterns are expressed as microscopic branching aggregates (clusters) of aragonite disseminated throughout the serpentinites. Aragonite growth was the final mineralization event. The aragonite diminishes rapidly in quantity from an essential to a trace component of the serpentinite over a distance of approximately 40 m from a normal fault. Decreasing abundance of aragonite away from the normal fault links the growth of the carbonate to the multistage hydrothermal mineralization associated with the fault. Aragonite clusters are concentrated in picrolite, where they are interwoven with colloid-sized chrysotile, and show fractal growth habits. Areas adjacent to the clusters are sites of Mg enrichment of the serpentine medium relative to aragonite-free picrolite. It is interpreted that the aragonite clusters result from incursions of reactive seawater solutions through fine-scale pore structures in and around the fault in response to pressure gradients emanating from active tectonism. Cluster growth is interpreted to be a percolation phenomenon and provides a novel source of information on the nature of fine-scale reactive fluid flow, pore-space connectivity, and carbonate replacement processes in serpentinites.
English
Serial
Coverage:Geographic coordinates:
North:41.0000
West:-15.3000East: -10.2000
South:39.0000

Igneous and metamorphic petrology; Mineralogy of non-silicates; aragonite; Atlantic Ocean; carbonates; crystal growth; fractals; hydrothermal conditions; Iberian abyssal plain; igneous rocks; Leg 173; metaigneous rocks; metamorphic rocks; metasomatic rocks; mineralization; North Atlantic; Northeast Atlantic; Ocean Drilling Program; picrolite; plutonic rocks; sea water; serpentinite; ultramafics; viscous materials;

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