Damuth, John E. and Balsam, William L. (2004): Spectral data from Sites 1165 and 1167 including the HiRISC section from Hole 1165B

Leg/Site/Hole:
ODP 188
ODP 188 1165
ODP 188 1167
Identifier:
2004-083819
georefid

10.2973/odp.proc.sr.188.003.2003
doi

Creator:
Damuth, John E.
University of Texas at Arlington, Department of Geology, Arlington, TX, United States
author

Balsam, William L.
Australian Geological Survey Organisation, Australia
author

Identification:
Spectral data from Sites 1165 and 1167 including the HiRISC section from Hole 1165B
2004
In: Cooper, Alan K., O'Brien, Philip E., Richter, Carl, Barr, Samantha R., Bohaty, Steven M., Claypool, George E., Damuth, John E., Erwin, Patrick S., Florindo, Fabio, Forsberg, Carl Fredrik, Gruetzner, Jens, Handwerger, David A., Januszczak, Nicole N., Kaiko, Alexander, Kryc, Kelly A., Lavelle, Mark, Passchier, Sandra, Pospichal, James J., Quilty, Patrick G., Rebesco, Michele A., Strand, Kari O., Taylor, Brian, Theissen, Kevin M., Warnke, Detlef A., Whalen, Patricia A., Whitehead, Jason M., Williams, Trevor, Proceedings of the Ocean Drilling Program; scientific results; Prydz Bay-Cooperation Sea, Antarctica; glacial history and paleoceanography; covering Leg 188 of the cruises of the drilling vessel JOIDES Resolution; Fremantle, Australia, to Hobart, Tasmania; Sites 1165-1167; 10 January-11 March 2000
Texas A&M University, Ocean Drilling Program, College Station, TX, United States
188
We measured and analyzed near-ultraviolet/visible/near-infrared spectral data from core samples recovered from Ocean Drilling Program Sites 1165 (Wild Drift) and 1167 (Prydz Channel Trough Mouth Fan) using our laboratory-grade spectrophotometer to help determine temporal mineralogical changes downhole. These measurements included closely spaced ( approximately 10 cm) samples for the section from 0 to 54.17 meters below seafloor (mbsf) in Hole 1165B, which is the Pliocene-Pleistocene age interval being studied in detail by the High-Resolution Integrated Stratigraphy Committee (HiRISC). We also determined calcium carbonate content for all samples in this HiRISC interval. The Pleistocene and uppermost Pliocene sediments (0-10 mbsf) show wide carbonate fluctuations ranging from 0 to 37 wt%; however, below 10 mbsf, the carbonate content is generally zero. To examine the major components that contribute to spectral variability in the holes, the first-derivative values for all samples from Sites 1165 and 1167 were assembled into a single matrix and the matrix was then factor analyzed after being subject to a varimax rotation. For Sites 1165 and 1167, factoring first-derivative values from 255 to 745 nm produced the most easily interpretable results, with five factors that explain approximately 92.5% of the total variance in the data set. Factor 1 incorporates both goethite and chlorite, meaning that scores for this factor will be high where these two minerals covary. Factor 2 is interpreted as organic matter. Factor 3 appears to be a combination of clay minerals, possibly montmorillonite and illite. Factor 4 is interpreted as the mineral maghemite, a polymorph of hematite. Factor 5 is the mineral hematite. We generated plots of factor scores downhole at Sites 1165 and 1167 to determine trends in temporal changes. At Site 1165 Factor 1 predominates above approximately 540 mbsf, Factor 2 is important above approximately 280 mbsf, and Factor 3 is high from 25 to 350 mbsf. Factor 4 exhibits two zones of high values from 20 to 50 mbsf and 540 to 750 mbsf. Factor 5 is important from 0 to 95 mbsf. In the HiRISC Section of Hole 1165B (0-54 mbsf), Factors 1 and 2 exhibit high scores through most of the section, with the exception of a low in both factors centered at approximately 30 mbsf. Factors 3 and 4 exhibit high values primarily below 30 mbsf, and Factor 5 exhibits higher-frequency variation than the other factors. Despite apparent similarities in their downhole patterns, few of the factors are highly correlated to each other. In Hole 1167A Factor 1 is important only in the top 5 mbsf, whereas Factor 2 is important throughout the entire hole. Factor 3 is important only from 210 to 227 mbsf, Factor 4 exhibits a few high values in the uppermost 30 mbsf, and Factor 5 is most important from 30 to 210 mbsf. Regression of factor scores vs. X-ray diffraction percentage values for the various minerals downhole indicates minor correlations of Factor 1 to pyrite and Factor 2 to hornblende. No other factors exhibited a correlation >0.1 for any of the minerals analyzed.
English
Coverage:Geographic coordinates:
North:-64.2200
West:67.1300East: 72.1800
South:-66.2400

Oceanography; brightness; calcium carbonate; density; experimental studies; glacial environment; glaciomarine environment; grain size; laboratory studies; Leg 188; marine environment; marine sediments; mineral composition; near-infrared spectra; Ocean Drilling Program; ODP Site 1165; ODP Site 1167; Prydz Bay; regression analysis; sediments; Southern Ocean; spectra; statistical analysis; ultraviolet spectra; X-ray diffraction data;

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