Dickens, Gerald R. and Kennedy, B. Mack (2000): Noble gases in methane hydrate from the Blake Ridge

Leg/Site/Hole:
ODP 164
ODP 164 994
ODP 164 996
ODP 164 997
Identifier:
2001-025811
georefid

10.2973/odp.proc.sr.164.211.2000
doi

Creator:
Dickens, Gerald R.
James Cook University, School of Earth Sciences, Townsville, Queensl., Australia
author

Kennedy, B. Mack
University of Tokyo, Japan
author

Identification:
Noble gases in methane hydrate from the Blake Ridge
2000
In: Paull, Charles K., Matsumoto, Ryo, Wallace, Paul J., Black, Nancy R., Borowski, Walter S., Collett, Timothy S., Damuth, John E., Dickens, Gerald R., Egeberg, Per Kristian, Goodman, Kim, Hesse, Reinhard F., Hiroki, Yoshihisa, Holbrook, W. Steven, Hoskins, Hartley, Ladd, John, Lodolo, Emanuele, Lorenson, Thomas D., Musgrave, Robert J., Naehr, Thomas H., Okada, Hisatake, Pierre, Catherine, Ruppel, Carolyn D., Satoh, Mikio, Thiery, Regis, Watanabe, Yoshio, Wehner, Hermann, Winters, William J., Wood, Warren T., Miller, Christine M. (editor), Reigel, Ruth (editor), Proceedings of the Ocean Drilling Program; volume 164; scientific results; gas hydrate sampling on the Blake Ridge and Carolina Rise; covering Leg 164 of the cruises of the drilling vessel JOIDES Resolution, Halifax, Nova Scotia, to Miami, Florida, sites 991-997, 31 October-19 December 1995
Texas A & M University, Ocean Drilling Program, College Station, TX, United States
164
165-170
Fractionation of the noble gases should occur during formation of a Structure I gas hydrate from water and CH (sub 4) such that CH (sub 4) hydrate is greatly enriched in Xenon. Noble gas concentrations and fractionation factors (F[ (super 4) He], F[ (super 22) Ne], F[ (super 86) Kr], and F[ (super 132) Xe] as well as R/R (sub a) ) were determined for eight gas hydrate specimens collected on Leg 164 to evaluate this theoretical possibility and to assess whether sufficient quantities of Xe are hosted in oceanic CH (sub 4) hydrate to account for Xe "missing" from the atmosphere. The simplest explanation for our results is that samples contain mixtures of air and two end-member gases. One of the end-member gases is depleted in Ne, but significantly enriched in Kr and Xe, as anticipated if the source of this gas involves fractionation during Structure I gas hydrate formation. However, although oceanic CH (sub 4) hydrate may be greatly enriched in Xe, simple mass balance calculations indicate that oceanic CH (sub 4) hydrate probably represents only a minor reservoir of terrestrial Xe. Noble gas analyses may play an important role in understanding the dynamics of gas hydrate reservoirs, but significantly more work is needed than presented here.
English
Serial
Coverage:Geographic coordinates:
North:32.2938
West:-76.1127East: -75.2807
South:31.4708

Isotope geochemistry; aliphatic hydrocarbons; alkanes; Ar-36; argon; Atlantic Ocean; atmosphere; Blake-Bahama Outer Ridge; gas hydrates; hydrocarbons; isotope fractionation; isotopes; Leg 164; methane; noble gases; North Atlantic; Ocean Drilling Program; ODP Site 994; ODP Site 996; ODP Site 997; organic compounds; porosity; stable isotopes; Xe-132; xenon;

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