Kono, Masaru et al. (1980): Fe-Ti oxide mineralogy of DSDP Leg 55 basalts

Leg/Site/Hole:
DSDP 55
DSDP 55 430
DSDP 55 432
DSDP 55 433
Identifier:
1981-027020
georefid

10.2973/dsdp.proc.55.126.1980
doi

Creator:
Kono, Masaru
Middlebury Coll., Middlebury, VT, United States
author

Clague, David
Univ. Colo., Boulder, CO, United States
author

Larson, Edwin E.
author

Identification:
Fe-Ti oxide mineralogy of DSDP Leg 55 basalts
1980
In: Shambach, James (editor), Jackson, Everett Dale, Koizumi, Itaru, Avdeiko, Gennady, Butt, Arif, Clague, David, Dalrymple, G. Brent, Greene, H. Gary, Karpoff, Anne Marie, Kirkpatrick, R. James, Kono, Masaru, Hsin Yi Ling, McKenzie, Judith, Morgan, Jason, Takayama, Toshiaki, Initial reports of the Deep Sea Drilling Project covering Leg 55 of the cruises of the drilling vessel Glomar Challenger, Honolulu, Hawaii to Yokohama, Japan; July-September 1977
Texas A & M University, Ocean Drilling Program, College Station, TX, United States
55
639-652
Fe-Ti oxides in Leg 55 basalts were analyzed by optical microscope, scanning electron microscope, and X-ray microanalyzer. Substantial differences exist between the states of ferromagnetic minerals in the present samples and in typical oceanic basalts. Leg 55 basalts are characterized by universal occurrence of high-temperature oxidation, a high magnetic stability in consequence of the small effective grain size, and a wide range of composition of the titanomagnetite phase. These are typical properties of subaerial basalts. From these observations, we conclude that Leg 55 basalts (and perhaps most of the Emperor Seamounts basalts) were subaerially erupted, and that subsidence into the sea of the volcanic islands at later dates did not appreciably change the original ferromagnetic minerals. We do not support the widespread opinion that titanomagnetites in basalts of any origin alter to titanomaghemite at ambient temperatures if the basalts are submerged under the sea for a sufficiently long period of time ( approximately 107 years, e.g., Ozima et al., 1974). Leg 55 basalts also contain some titanomaghemites. The degree of low-temperature oxidation in Leg 55 basalts is usually quite low. Low-temperature oxidation is confined to samples where high-temperature oxidation was of low or low to moderate degree, but none of the H and M-H samples contain titanomaghemite. Low-temperature oxidation is abundant in Hole 432A (Nintoku) and absent in Hole 430A (Ojin). In Hole 433C (Suiko), the occurrence of low temperature oxidation is not related to either type of rock or depth below the sea floor. Observations by SEM reveal lamellar structure at a fraction of a micrometer. When ilmenite (and other) lamellae are well developed, the host becomes almost pure magnetite. The existence of spinel lamellae at fine scale was found by X-ray energy-dispersive spectrum. The subdivision of magnetite host by lamellae is undoubtedly related to the nearly single-domain-like stability of magnetization in these rocks. Because of such fine-scale structures in Fe-Ti oxides, we point out the inherent ambiguity in application of the Buddington-Lindsley method to estimate the "last" equilibrium temperatures and oxygen fugacities.
English
Coverage:Geographic coordinates:
North:50.0000
West:160.0000East: 175.0000
South:35.0000

Igneous and metamorphic petrology; basalts; composition; Deep Sea Drilling Project; Emperor Seamounts; ferromagnetic minerals; geochemistry; igneous rocks; ilmenite; IPOD; Leg 55; magnetic minerals; magnetic properties; mineral composition; North Pacific; Northwest Pacific; ocean floors; oxidation; oxides; Pacific Ocean; petrology; processes; SEM data; Site 430; Site 432; Site 433; titanomagnetite; volcanic rocks; West Pacific;

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