Balsam, William L. and Damuth, John E. (2000): Further investigations of shipboard vs. shore-based spectral data; implications for interpreting Leg 164 sediment composition

Leg/Site/Hole:
ODP 164
Identifier:
2001-025826
georefid

10.2973/odp.proc.sr.164.222.2000
doi

Creator:
Balsam, William L.
University of Texas at Arlington, Department of Geology, Arlington, TX, United States
author

Damuth, John E.
University of Tokyo, Japan
author

Identification:
Further investigations of shipboard vs. shore-based spectral data; implications for interpreting Leg 164 sediment composition
2000
In: Paull, Charles K., Matsumoto, Ryo, Wallace, Paul J., Black, Nancy R., Borowski, Walter S., Collett, Timothy S., Damuth, John E., Dickens, Gerald R., Egeberg, Per Kristian, Goodman, Kim, Hesse, Reinhard F., Hiroki, Yoshihisa, Holbrook, W. Steven, Hoskins, Hartley, Ladd, John, Lodolo, Emanuele, Lorenson, Thomas D., Musgrave, Robert J., Naehr, Thomas H., Okada, Hisatake, Pierre, Catherine, Ruppel, Carolyn D., Satoh, Mikio, Thiery, Regis, Watanabe, Yoshio, Wehner, Hermann, Winters, William J., Wood, Warren T., Miller, Christine M. (editor), Reigel, Ruth (editor), Proceedings of the Ocean Drilling Program; volume 164; scientific results; gas hydrate sampling on the Blake Ridge and Carolina Rise; covering Leg 164 of the cruises of the drilling vessel JOIDES Resolution, Halifax, Nova Scotia, to Miami, Florida, sites 991-997, 31 October-19 December 1995
Texas A & M University, Ocean Drilling Program, College Station, TX, United States
164
313-324
Diffuse reflectance spectra measured during shipboard core description with a hand-held Minolta spectrophotometer are reliable data for interpreting sediment composition. Factor analysis of these spectra indicates that only Glad Cling Wrap (super TM) , a polyethylene food wrap, should be used to cover wet cores during measurement because it introduces substantially less noise into the spectra than other brands of plastic food wrap. This validates our previous recommendation that only Glad Cling Wrap (super TM) should be used to cover wet core surfaces before spectral analysis on board ship. Factor analysis also indicates that the red end of the spectrum was a little noisy; however, it is unclear if this noise was produced by the Glad Cling Wrap (super TM) , by the Minolta instrument, or by the sediment being analyzed when wet (water tends to affect the red end of the spectrum more than the violet). Comparison of spectra taken directly from wet cores on board ship with the Minolta CM-2002 to those taken from dried, prepared samples with our shore-based Perkin-Elmer Lambda 6 spectrophotometer indicates that water mutes the spectral signal. Although factor analysis of the Perkin-Elmer data produced five factors, four of those factors are the same as the factors extracted from the wet core data with the Minolta. This suggests that the water content in the wet cores was not high enough to seriously hinder interpretation of sediment composition. These four common factors are interpreted as carbonate, chlorite or glauconite, organic matter, and iron oxides (probably a mixture of hematite and goethite). The presence of hematite can be attributed to hematite-rich sediment derived from the Canadian Maritime provinces, which has been transported southward by the Western Boundary Undercurrent (WBUC) along North American continental margin. Based on the distribution of hematite down the Leg 164 holes, the WBUC apparently has washed over the Leg 164 sites on the crest of the Blake Ridge only during the Holocene and very latest Pleistocene.
English
Serial
Coverage:Geographic coordinates:
North:34.0000
West:-82.0000East: -74.0000
South:28.0000

General geochemistry; Oceanography; accuracy; Atlantic Ocean; Blake-Bahama Outer Ridge; carbonates; Cenozoic; clay mineralogy; cores; diffuse reflectance spectra; factor analysis; hematite; Holocene; instruments; Leg 164; marine sediments; measurement; methods; mineral composition; North Atlantic; Ocean Drilling Program; oxides; Pleistocene; Quaternary; sample preparation; sediments; statistical analysis; upper Pleistocene; water content;

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