Holm, Nils G. et al. (2006): Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents; a hypothesis

Leg/Site/Hole:
ODP 201
Identifier:
2008-004653
georefid

1467-4866
issn

10.1186/1467-4866-7-7
doi

Creator:
Holm, Nils G.
Stockholm University, Department of Geology and Geochemistry, Stockholm, Sweden
author

Dumont, Marion
author

Ivarsson, Magnus
author

Konn, Cecile
author

Identification:
Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents; a hypothesis
2006
Geochemical Transactions
BioMed Central, London, United Kingdom
7
7
Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150 degrees C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other--brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor.
English
Coverage:Geographic coordinates:
North:22.3000
West:-110.3500East: 149.0000
South:-12.0500

Geochemistry of rocks, soils, and sediments; alkalic composition; biogenic processes; brucite; ferromanganese composition; fluid phase; geochemistry; hydrothermal conditions; hydroxides; igneous rocks; Leg 201; Mariana Islands; Mariana Trench; Micronesia; North Pacific; Northwest Pacific; nucleic acids; Ocean Drilling Program; ocean floors; Oceania; organic compounds; oxides; Pacific Ocean; pH; plutonic rocks; proteins; purines; RNA; sea water; ultramafics; West Pacific;

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