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Holm, Nils G. et al. (2006): Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents; a hypothesis
Leg/Site/Hole:
Related Expeditions:
ODP 201
Identifier:
ID:
2008-004653
Type:
georefid
ID:
1467-4866
Type:
issn
ID:
10.1186/1467-4866-7-7
Type:
doi
Creator:
Name:
Holm, Nils G.
Affiliation:
Stockholm University, Department of Geology and Geochemistry, Stockholm, Sweden
Role:
author
Name:
Dumont, Marion
Affiliation:
Role:
author
Name:
Ivarsson, Magnus
Affiliation:
Role:
author
Name:
Konn, Cecile
Affiliation:
Role:
author
Identification:
Title:
Alkaline fluid circulation in ultramafic rocks and formation of nucleotide constituents; a hypothesis
Year:
2006
Source:
Geochemical Transactions
Publisher:
BioMed Central, London, United Kingdom
Volume:
7
Issue:
7
Pages:
Abstract:
Seawater is constantly circulating through oceanic basement as a low-temperature hydrothermal fluid (<150 degrees C). In cases when ultramafic rocks are exposed to the fluids, for instance during the initial phase of subduction, ferromagnesian minerals are altered in contact with the water, leading to high pH and formation of secondary magnesium hydroxide, among other--brucite, that may scavenge borate and phosphate from seawater. The high pH may promote abiotic formation of pentoses, particularly ribose. Pentoses are stabilized by borate, since cyclic pentoses form a less reactive complex with borate. Analyses have shown that borate occupies the 2' and 3' positions of ribose, thus leaving the 5' position available for reactions like phosphorylation. The purine coding elements (adenine, in particular) of RNA may be formed in the same general hydrothermal environments of the seafloor.
Language:
English
Genre:
Serial
Rights:
URL:
http://www.geochemicaltransactions.com/content/pdf/1467-4866-7-7.pdf
Coverage:
Geographic coordinates:
North:22.3000
West:-110.3500
East: 149.0000
South:-12.0500
Keywords:
Geochemistry of rocks, soils, and sediments; alkalic composition; biogenic processes; brucite; ferromanganese composition; fluid phase; geochemistry; hydrothermal conditions; hydroxides; igneous rocks; Leg 201; Mariana Islands; Mariana Trench; Micronesia; North Pacific; Northwest Pacific; nucleic acids; Ocean Drilling Program; ocean floors; Oceania; organic compounds; oxides; Pacific Ocean; pH; plutonic rocks; proteins; purines; RNA; sea water; ultramafics; West Pacific;
.
Copyright © 2006-2007 IODP-MI