Klauda, Jeffrey B. and Sandler, Stanley I. (2005): Global distribution of methane hydrate in ocean sediment

Leg/Site/Hole:
ODP 164
ODP 164 994
ODP 164 995
ODP 164 997
Identifier:
2005-053912
georefid

10.1021/ef049798o
doi

Creator:
Klauda, Jeffrey B.
University of Delaware, Department of Chemical Engineering, Newark, DE, United States
author

Sandler, Stanley I.
author

Identification:
Global distribution of methane hydrate in ocean sediment
2005
Energy & Fuels
American Chemical Society, Washington, DC, United States
19
2
459-470
In this paper, we present an equilibrium thermodynamic model to accurately predict the maximum depth of hydrate stability in the seafloor, including the effects of water salinity, hydrate confinement in pores, and the distribution of pore sizes in natural sediments. This model uses sediment type, geothermal gradient, and seafloor depth as input to predict the thickness of the hydrate zone. Using this hydrate model and a mass-transfer description for hydrate formation, we have also developed a predictive method for the occurrence of methane hydrates in the ocean. Based on this information, a prediction for the distribution of methane hydrate in ocean sediment is presented on a 1 degrees latitude by 1 degrees longitude (1 degrees X1 degrees ) global grid. From this detailed prediction, we estimate that there is a total volume of 1.2X10 (super 17) m (super 3) of methane gas (expanded to atmospheric conditions), or, equivalently, 74 400 Gt of CH (sub 4) in ocean hydrates, which is 3 orders of magnitude larger than worldwide conventional natural gas reserves. Of this number, we estimate that 4.4X10 (super 16) m (super 3) of methane expanded to standard temperature and pressure (STP) exists on the continental margins.
Coverage:Geographic coordinates:
North:31.5035
West:-75.3245East: -75.2807
South:31.4708

Economic geology, geology of energy sources; Oceanography; aliphatic hydrocarbons; alkanes; chemical composition; continental margin; equations; gas hydrates; geochemistry; geothermal gradient; heat flow; hydrocarbons; latitude; Leg 164; marine geology; marine sediments; mass transfer; mathematical methods; methane; models; natural gas; Ocean Drilling Program; ocean floors; ODP Site 994; ODP Site 995; ODP Site 997; organic compounds; P-T conditions; petroleum; petroleum exploration; phase equilibria; physical properties; porosity; prediction; reserves; sea water; sediments; thermodynamic properties; total organic carbon; world ocean;

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