Heydolph, Ken et al. (2012): Along and across arc geochemical variations in NW Central America; evidence for involvement of lithospheric pyroxenite

Leg/Site/Hole:
DSDP 67
DSDP 67 495
Identifier:
2012-061448
georefid

10.1016/j.gca.2012.01.035
doi

Creator:
Heydolph, Ken
University of Kiel, Kiel, Germany
author

Hoernle, Kaj
Leibniz-Institut fur Meereswissenschaften, Germany
author

Hauff, Folkmar
University of Oregon, United States
author

van der Bogaard, Paul
author

Portnyagin, Maxim
author

Bindeman, Ilya
author

Garbe-Schoenberg, Dieter
author

Identification:
Along and across arc geochemical variations in NW Central America; evidence for involvement of lithospheric pyroxenite
2012
Geochimica et Cosmochimica Acta
Elsevier, New York, NY, International
84
459-491
The Central American Volcanic Arc (CAVA) has been the subject of intensive research over the past few years, leading to a variety of distinct models for the origin of CAVA lavas with various source components. We present a new model for the NW Central American Volcanic Arc based on a comprehensive new geochemical data set (major and trace element and Sr-Nd-Pb-Hf-O isotope ratios) of mafic volcanic front (VF), behind the volcanic front (BVF) and back-arc (BA) lava and tephra samples from NW Nicaragua, Honduras, El Salvador and Guatemala. Additionally we present data on subducting Cocos Plate sediments (from DSDP Leg 67 Sites 495 and 499) and igneous oceanic crust (from DSDP Leg 67 Site 495), and Guatemalan (Chortis Block) granitic and metamorphic continental basement. We observe systematic variations in trace element and isotopic compositions both along and across the arc. The data require at least three different endmembers for the volcanism in NW Central America. (1) The NW Nicaragua VF lavas require an endmember with very high Ba/(La, Th) and U/Th, relatively radiogenic Sr, Nd and Hf but unradiogenic Pb and low delta (super 18) O, reflecting a largely serpentinite-derived fluid/hydrous melt flux from the subducting slab into a depleted N-MORB type of mantle wedge. (2) The Guatemala VF and BVF mafic lavas require an enriched endmember with low Ba/(La, Th), U/Th, high delta (super 18) O and radiogenic Sr and Pb but unradiogenic Nd and Hf isotope ratios. Correlations of Hf with both Nd and Pb isotopic compositions are not consistent with this endmember being subducted sediments. Granitic samples from the Chiquimula Plutonic Complex in Guatemala have the appropriate isotopic composition to serve as this endmember, but the large amounts of assimilation required to explain the isotope data are not consistent with the basaltic compositions of the volcanic rocks. In addition, mixing regressions on Nd vs. Hf and the Sr and O isotope plots do not go through the data. Therefore, we propose that this endmember could represent pyroxenites in the lithosphere (mantle and possibly lower crust), derived from parental magmas for the plutonic rocks. (3) The Honduras and Caribbean BA lavas define an isotopically depleted endmember (with unradiogenic Sr but radiogenic Nd, Hf and Pb isotope ratios), having OIB-like major and trace element compositions (e.g. low Ba/(La, Th) and U/Th, high La/Yb). This endmember is possibly derived from melting of young, recycled oceanic crust in the asthenosphere upwelling in the back-arc. Mixing between these three endmember types of magmas can explain the observed systematic geochemical variations along and across the NW Central American Arc. Abstract Copyright (2012) Elsevier, B.V.
English
Serial
Coverage:Geographic coordinates:
North:14.0000
West:-91.0216East: -82.0000
South:10.0000

Geochemistry of rocks, soils, and sediments; Igneous and metamorphic petrology; alkaline earth metals; back-arc basins; basins; Central America; Chiquimula Complex; Cocos Plate; Deep Sea Drilling Project; DSDP Site 495; East Pacific; El Salvador; Equatorial Pacific; geochemistry; granites; Guatemala; hafnium; ICP mass spectra; igneous rocks; IPOD; island arcs; isotope ratios; isotopes; lava; lead; Leg 67; lithogeochemistry; lithosphere; major elements; mass spectra; metals; Nd-144/Nd-143; neodymium; Nicaragua; North Pacific; Northeast Pacific; O-18/O-16; oceanic lithosphere; oxygen; Pacific Ocean; plate tectonics; plutonic rocks; pyroxenite; rare earths; spectra; Sr-87/Sr-86; stable isotopes; strontium; trace elements; ultramafics; volcanic rocks; X-ray fluorescence spectra;

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