Oehlert, Amanda M. et al. (2010): The relationship between the Delta (super 13) C of inorganic and organic components in Neogene periplatform sediments; implications for the Proterozoic

Leg/Site/Hole:
ODP 166
ODP 166 1005
ODP 166 1006
Identifier:
2011-086975
georefid

Creator:
Oehlert, Amanda M.
Rosenstiel School of Marine and Atmospheric Sciences, Miami, FL, United States
author

Swart, Peter K.
author

Devlin, Quinn B.
author

Identification:
The relationship between the Delta (super 13) C of inorganic and organic components in Neogene periplatform sediments; implications for the Proterozoic
2010
In: Anonymous, Geological Society of America, 2010 annual meeting
Geological Society of America (GSA), Boulder, CO, United States
42
5
299
Covariance of delta (super 13) C values of inorganic and organic fractions of pelagic carbonate sediments has been used to interpret rates of organic carbon production, burial and decomposition through time. This relationship is relatively consistent in deep sea sediments, which permits estimates of organic carbon production and preservation. However, the majority of pelagic sediments older than 200 myr have since been subducted, therefore carbonate sediments deposited in epeiric seas and platforms are often substituted in studies of the Paleozoic carbon cycle. There are several well known pitfalls in using such sediments including diagenesis, semi-isolation of the depositional environment, and input of varying types of sediments with differing delta (super 13) C values. One method to assess that global changes in delta (super 13) C are accurately represented by inorganic delta (super 13) C is to examine variations in the delta (super 13) C of co-occurring organic material. If the delta (super 13) C (sub organic) covaries with delta (super 13) C (sub inorganic) it is argued that the signals must be related to the global delta (super 13) C values. This assumption was investigated by analyzing periplatform sediments drilled along a slope transect off the western margin of Great Bahama Bank. The delta (super 13) C (sub inorganic) was shown to correlate between all sites along the transect; however, these records were not related to the global carbon cycle. Instead, these variations relate to global sea-level changes which can initiate or terminate production of isotopically distinct sediment on the platform. At the sites studied, the correlation between delta (super 13) C (sub inorganic) and delta (super 13) C (sub organic) increased from the proximal site (1005, r (super 2) =0.1) to the more distal site (1006, r (super 2) =0.63). The absence of a covariance between delta (super 13) C (sub inorganic) and delta (super 13) C (sub organic) values at the proximal Site 1005 reflects the predominance of bank top sediment and organic material, which exhibit no correlation of delta (super 13) C (sub organic) and delta (super 13) C (sub inorganic) values. In contrast, distal Site 1006 is a two point mixing model consisting of platform sediments with enriched delta (super 13) C values, and relatively depleted ocean derived material. This results in a strong positive correlation between delta (super 13) C (sub inorganic) and delta (super 13) C (sub organic) records at Site 1006 that is unrelated to the global carbon cycle. Such data question the use of the delta (super 13) C (sub organic) values to support the global nature of the delta (super 13) C (sub inorganic) values.
English
Coverage:Geographic coordinates:
North:24.3346
West:-79.2733East: -79.1408
South:24.2359

Isotope geochemistry; Stratigraphy; Atlantic Ocean; burial; C-13/C-12; carbon; carbon cycle; carbonate platforms; carbonates; Cenozoic; covariance analysis; depositional environment; diagenesis; epicontinental seas; geochemical cycle; global; Great Bahama Bank; inorganic materials; isotope ratios; isotopes; Leg 166; marine sediments; Neogene; North Atlantic; Ocean Drilling Program; ODP Site 1005; ODP Site 1006; organic carbon; Paleozoic; pelagic environment; Precambrian; Proterozoic; sediments; stable isotopes; statistical analysis; Straits of Florida; Tertiary; upper Precambrian;

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