Moebius, Juergen et al. (2011): Influence of diagenesis on sedimentary delta (super 15) N in the Arabian Sea over the last 130 kyr

Leg/Site/Hole:
ODP 117
ODP 117 722
ODP 117 724
Identifier:
2011-062874
georefid

10.1016/j.margeo.2011.03.013
doi

Creator:
Moebius, Juergen
University of Hamburg, Institute of Biogeochemistry and Marine Chemistry, Hamburg, Germany
author

Gaye, Birgit
author

Lahajnar, Niko
author

Bahlmann, Enno
author

Emeis, Kay-Christian
author

Identification:
Influence of diagenesis on sedimentary delta (super 15) N in the Arabian Sea over the last 130 kyr
2011
Marine Geology
Elsevier, Amsterdam, Netherlands
284
1-4
127-138
Sedimentary delta (super 15) N records are valuable archives of ocean history but they are often modified during early diagenesis. Here we quantify the effect of early diagenetic enrichment on sedimentary N-isotope composition in order to obtain the pristine signal of reactive N assimilated in the euphotic zone. This is possible by using paired data of delta (super 15) N and amino acid composition of sediment samples, which can be applied to estimate the degree of organic matter degradation. We determined delta (super 15) N and amino acid composition in coeval sediments from Ocean Drilling Program (ODP) Hole 772 B in the central Arabian Sea and from Hole 724 C situated on the Oman Margin in the western Arabian Sea coastal upwelling area. The records span the last 130 kyr and include two glacial-interglacial cycles. These new data are used in conjunction with data available for surface sediments that cover a wide range of organic matter degradation states, and with other cores from the northern and eastern Arabian Sea to explore spatial variations in the isotopic signal. In order to reconstruct pristine N values we apply the relationship between organic matter degradation and (super 15) N enrichment in surface sediments to correct the core records for early diagenetic enrichment. Reconstructed delta (super 15) N values suggest a significant role of N (sub 2) -fixation during glacial stages. An evaluation of two preservation indices based on amino acid composition (Reactivity Index, RI; Jennerjahn and Ittekkot, 1997; and the Degradation Index, DI; Dauwe et al., 1999) in both recent sediments and core samples suggests that the RI is more suitable than the DI in correcting Arabian Sea delta (super 15) N records for early diagenetic enrichment. Abstract Copyright (2011) Elsevier, B.V.
English
Serial
Coverage:Geographic coordinates:
North:23.0600
West:57.4708East: 68.3500
South:15.3600

Quaternary geology; Isotope geochemistry; amino acids; Arabian Sea; Cenozoic; cores; denitrification; diagenesis; early diagenesis; Holocene; Indian Ocean; isotope ratios; isotopes; Leg 117; marine environment; marine sediments; N-15/N-14; nitrogen; Ocean Drilling Program; ODP Site 722; ODP Site 724; organic acids; organic compounds; paleoenvironment; Pleistocene; preservation; Quaternary; sediments; stable isotopes; upper Pleistocene;

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