Borowski, Walter S. (2005): Dissolved sulfide concentration and sulfur isotopic composition of sulfide and sulfate in pore waters, ODP Leg 204, Hydrate Ridge and vicinity, Cascadia margin, offshore Oregon. Texas A&M University, Ocean Drilling Program, College Station, TX, United States, In: Trehu, Anne M., Bohrmann, Gerhard, Torres, Marta E., Rack, Frank R., Bangs, Nathan L., Barr, Samantha R., Borowski, Walter S., Claypool, George E., Collett, Timothy S., Delwiche, Mark E., Dickens, Gerald R., Goldberg, David S., Gracia, Eulalia, Guerin, Gilles, Holland, Melanie, Johnson, Joel E., Lee, Young-Joo, Liu, Char-Shine, Long, Philip E., Milkov, Alexei V., Riedel, Michael, Schultheiss, Peter, Su Xin, Teichert, Barbara, Tomaru, Hitoshi, Vanneste, Maarten, Watanabe, Mahito, Weinberger, Jill L., Boetius, Antje, Brockman, Fred J., Deyhle, Annette, Fehn, Udo, Flemings, Peter B., Girguis, Peter R., Heesemann, Martin, Joye, Samantha B., Lorenson, Thomas D., Mills, Christopher T., Musgrave, Robert J., Popa, Radu, Ussler, Bill, Wilkes, Heinz, Winckler, Gisela, Winters, William J., Proceedings of the Ocean Drilling Program; scientific results; drilling gas hydrates on Hydrate Ridge, Cascadia continental margin; covering Leg 204 of the cruises of the drilling vessel JOIDES Resolution; Victoria, British Columbia, Canada, to Victoria, British Columbia, Canada; Sites 1244-1252; 7 July-2 September 2002, 204, georefid:2007-035107

Abstract:
We report dissolved sulfide sulfur concentrations and the sulfur isotopic composition of dissolved sulfate and sulfide in pore waters from sediments collected during Ocean Drilling Program Leg 204. Porewater sulfate is depleted rapidly as the depth to the sulfate/methane interface (SMI) occurs between 4.5 and 11 meters below seafloor at flank and basin locations. Dissolved sulfide concentration reaches values as high as 11.3 mM in Hole 1251E. Otherwise, peak sulfide concentrations lie between 3.2 and 6.1 mM and occur immediately above the SMI. The sulfur isotopic composition of interstitial sulfate generally becomes enriched in (super 34) S with increasing sediment depth. Peak delta (super 34) S-SO (sub 4) values occur just above the SMI and reach up to 53.1% Vienna Canyon Diablo Troilite (VCDT) in Hole 1247B. delta (super 34) S-Sigma HS values generally parallel the trend of delta (super 34) S-SO (sub 4) values but are more depleted in (super 34) S relative to sulfate, with values from -12.7% to 19.3% VCDT. Curvilinear sulfate profiles and carbon isotopic composition of total dissolved carbon dioxide at flank and basin sites strongly suggest that sulfate depletion is controlled by oxidation of sedimentary organic matter, despite the presence of methane gas hydrates in underlying sediments. Preliminary data from sulfur species are consistent with this interpretation for Leg 204 sediments at sites not located on or near the crest of Hydrate Ridge.
Coverage:
West: -125.0900 East: -125.0400 North: 44.3500 South: 44.3400
Relations:
Expedition: 204
Supplemental Information:
Data report; available only on CD-ROM in PDF format and on the Web in PDF or HTML
Data access:
Provider: SEDIS Publication Catalogue
Data set link: http://sedis.iodp.org/pub-catalogue/index.php?id=10.2973/odp.proc.sr.204.105.2006 (c.f. for more detailed metadata)
Data download: application/pdf
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